Yep. Once you've removed the sealed, the grooves need a damn good clean. The best method I've found is to find an allen key that will just fit in the groove, turn it slightly so it fills the groove and keep running it around until all the crap comes out. Both of these seal grooves need to be spotless. The groove on the piston less so, but still important when you put new pads in. Then the piston wants cleaning, which can be tricky finding something to remove rust without overly scratching the surface. This is without overly cleaning the outside, which is normally petrol in a washing up bowl and paint brush clean.
We are on the same page then
I prefer gunwash or standard thinners over petrol as it's a better solvent, smells better, and doesn't leave as much as a residue. Aircraft get wiped down with avgas; you fill up your spraybottle when checking the fuel-drain taps.
I use a bent pick to clean the grooves, as that's one of its intended jobs. A couple of sharp engineer's scrapers are really handy; grind out of worn, small files if you don't want to buy them
As for the piston, some really fine wire wool used with oil works for me. Work around the circumference, not across it. If that damages the piston, it wasn't worth bothering with.