Maybe a sniff test to check for exhaust gas in coolant ?
This. There are a few options that could cause it, best to eliminate the most expensive first
Could be dodgy waterpump, but can a mechanical waterpump work intermittently ?![]()
If its got a plastic impeller that's started to break down you could have a bit of plastic fin inside the impeller chamber that gets in the way occasionally and stops the pump spinning. I had a similar issue with a clutch once where a piece of friction material had broken off and occasionally prevented the clutch from disengaging
.If you can whip the water pump off easily, I'd do this second, if exhaust gasses have been ruled out.
Third guess (and it would be a guess) would be a coolant cap as it could give you similar symptoms as a partially blocked rad but is easier and cheaper to change


....because these days it's apparently controversial to say a woman can't have a penis. 
