As Al says, check the fans
Looking at what happened, this is my take on it .............
Your travelling down the motorway at 70 plus 10%
Your engine is running perfect with the airflow keeping the engine temp perfect.
You slow down.
The engines still nice and hot BUT you have very little airflow SO the block thermostat opens and the radiator fans (should) kick in.
Due to the block stat opening, it tries to divert the water through the radiator but its pretty much blocked up with crap so the water doesn't flow and causing the block temperature to go through the roof
My advise is, take the car off the road for a few days.
Remove the radiator and empty it.
Blank off all outlets by one and fill it with Fernox or another suitable central heating flush agent.
Leave it in for 24 hours than swill it around and empty it out.
Repeat for as many times as time will allow then empty and flush out with a hose pipe.
Important bit Don't use a pressure washer or you will shag the radiator
Refit and see what's happening
If it still over heats then its probably a knackered radiator so it will need changing