In theory, hub faces should be clean /dry, without any grease. Although many use copper slip to reduce the issue of 'stuck on' wheels, other 'thinner' lubricants are better, as suggested, a high melting point grease, but only the mere thinnest of wipes, so that there is barely any on the disc / hub face. Really, copperslip should be only be applied thinly to the flange where the wheel centre sits.
Some believe a small amount of copperslip should be applied to the hub before new brake discs are fitted - again this is a no no, and the hub faces should be clean.
The reason behind this is that copperslip can cause the brake discs to run slightly out of true, and accelerate other issues such as brake judder. It's hard to comprehend that a small amount of copperslip could be a factor in these issues, but a 'smidgen' out at the hub represents a larger amount at the edge of the wheel.
I only ever put copperslip on the hub flange, not the face, and have never had an issue with a 'stuck on' alloy. A quick rub with a wire brush every wheel removal helps.