Sound very likley that the thermostatic rad valve has stuck our gone faulty on that rad. They can stick over the summer when they are closed a lot because its warm or could be in your case that because the fire is on so much it has been closed almost all the time. The rubber seat sticks to th inlet orifice.
A quick test to be sure it isnt an air lock. Close all your other radiators by turning the thermostatic valve down to minimum. Leave the faulty one fully open or take the head sensor off. Run the system Leave it about 10 mins or so and if your faulty rad gets hot it could be an air lock or balancing required.
If it doesnt get hot with all the others off then it is more than likley the thermostatic valve is stuck or faulty. Remove the head sensor of the vave body. Then try tapping the side of the valve body with a medium size spanner or adjustables to try and free the rubber seating inside the valve, you could even try tapping the pin on the top, but be very carefull, if you hit it to hard you can drive the pin straight though and you have a leak.
If this doesnt work, I think you need to replace the valve complete. Let me know how you go on or PM me.
