used to drive a hyundai lantra 1.6 dohc. that had a huge improvement running ultimate. 6/7 more mpg and it felt like another 10 horses under the bonnet.
put some in my 99 MV6, crap. 18 to the gallon no more speed, in fact it felt lumpy and rubbish. back to asda.
another time however, with the miggy, I bought an stp power pack - red bottle of cleaner and orange bottle of distilled high-octane kerosine (aka speed boost)
put the cleaner in a whole tank, car got better over the tank.
when that tank was empty I put 25 litres of asda petrol on top of the 'orange juice' (supposedly treats 60 litres)
now
that was a fun few days

noticed a remarkable improvement in performance and
very smooth tickover.
If you want to get more out of an x30xe by simply raising the octane then in my experience you need to raise the octane quite a lot. (4 or 5 points!)