Well I finally got there...
Got the manifold off without significant dramas, the stud had broken about 2mm sub-flush at an angle of about 20°. Tried drilling and 'easy-out' type thing, without any luck, really didn't want to give it heaps as I didn't want a snapped off easy-out in there.
Ended up making a drill guide out of a thick steel plate that fitted over the nearest two good (new) studs and had a 6.8mm hole through a hardened bush in the position required to drill. Worked unbelievably well
. Bit of careful work with a tap and I had a new stud in the original thread.
Couldn't have done it without a very diddy mains drill loaned by Stan, our lovely old neighbour.
New studs and gaskets all round, obviously. Total for parts and one or two tools bought <£50, I'm very chuffed, as is my girlfriend
.
Changed my theory about the cause of the stud failure, though still coolant related. Rather than the top-hose connection leaking/squirting, I'm fairly sure it was actually the thermostat housing-to-head where the leak was, new seal in there now.
Merry Christmas one and all, and thanks for the advice.