Ok, further to my previous post of a week or so back, I've now got the heating working properly.

Diagnosis was that the both motorised valves had broken microswitches. I had some really good tech support from Drayton which helped pin this down - with continuity checks etc. Due to the age of the valves (1999) they are a single unit - whereas the updated version has the valve body and separate/removable actuator/microswitch gubbins. Having a new boiler which controls the pump directly sort of masked the fault - which saw the pump running for long periods & just pumping around the bypass.
New valves sourced and fitted today, plus a full service on the boiler.
The final little twist was why exactly the earth breaker was tripping about once a day. Drayton suggested checking the tightness of all the connections in the junction box located in the airing cupboard. They were right, with there being several which were not at all tight. All sorted now and working as intended.
So, nice & toasty for Christmas.