Try boiling water... Soaking it for five mins in a pan should suffice
tried that to remove broken valve , I still had no success
I've not found boiling water to heat nylon tube enough, plus the tube becomes too slippery to hold securely.
A few seconds with a heat gun makes assembling vacuum pipe simple, but you do still need a lot of force. The pipe's appearance doesn't change, it just becomes softer. Holding the fitting vertically in the vice works for me. This is how I've made custom fuel injection pipes, and I've never had one fail.
I tried to remove that valve by holding the pipe in a flaring tool clamp in a vice trying to soften with heat gun in one hand & trying to screw it off with mole grips.. never budge it 1mm. in the end I sawed off the valve, so see what happens when I get new valve. I have put feelers out for the complete pipe so see what that brings.
The valve is barbed, and the pipe a shrink fit over it. Assembling needs confidence, a rigid hold on the valve and heat on the pipe. Get that lot right, and it won't come apart without cutting something. A quick slice along the pipe with a Stanley knife removes the valve in less time than it takes you to read this sentence.
This makes quick, cheap easy and safe fuel injection pipes, so is easily good enough for vacuum.I would buy some hose(£10 a metre if bought from an expensive source), a new valve(about £8), and assemble on the car. The valves are universal, so you could get one off anything if a new one isn't acceptable. It's a cup of coffee job. That's how long the custom Avenger one took me when I added a brake servo to an engine swapped car.