The basic requirement of an engine for fuel of a certain octane rating comes from the compression ratio or, for forced induction, a combination of the compression ratio and boost pressure.
If knock occurs, retarding the ignition timing and/or reducing the boost pressure allows the engine to run without damage but sacrificing power and economy.
On older engines, this was more of an issue, but a reasonably modern design of combustion chamber doesn't need particularly aggressive ignition advance to produce its' best power output so, for sane levels of compression such as are used in the Omega, there is plenty of margin before knock starts even on standard 95 RON unleaded.
You can't change the compression ratio, so you need a knock retard strategy to cope with very poor quality fuel, the likes of which probably doesn't get sold in the UK.
Forced induction changes things and some turbo/supercharged cars probably do reduce boost on 95 RON fuel.
If you wire up the engine with instrumentation as is done during development then yes, you can get a picture of what's happening in the combustion chamber by recording when the peak pressure occurs during combustion and checking for signs of knock with more sophisticated equipment than a standard knock sensor.
Without increasing the compression ratio, I doubt a V6 would respond to higher octane fuel - even if you remapped it, because an engine with a pent roof chamber and 10-ish :1 compression probably still has a good margin against knock when the ignition has been advanced to the point where you get no improvement in power.