I have had many 230V shocks (Uk is 230V officialy and has been for 16 years +!).
A few 200V DC kicks when I was working at Alsthom (we had a simulator with 200V DC all over it).....these are not pleasent as unlike AC, you remain stuck to the bloody thing!
Hvae done some live work on 11Kv.....big rubber gloves and a rubber mat. No real shock but you can feel a bit of a tingling and get a few static discharges.
Spark plug systems with upto 50Kv (the V6 for example puts out over 45Kv!)
As for 3 phase.....remember this, to get 415V shocks you need to contact 2 phases (Very unlikely) as each phase is 230V with 415 between the 2. So those who have contacted 3 phase setups, chances are you only (although still bad enough!) were exposed to 230V.
The danger of course is the current.....its this that does the damage and much more than 25mA is considered an issue particularly if it travels across the chest cavity.
That said, the UK mains setup is about the best on the planet (the US is pretty poor despite the lower voltage!) with plenty of earths, well proctected socket setups and the latest regs requiring all circuits to have 30mA ELCB's.