Don't need a Tech2 either. A £5.99 multimeter across the battery is probably more accurate! Do make sure it's on the Volts range first though - NOT Amps!
I would follow this procedure:
Battery voltage - Engine stopped, rested battery, all loads turned off:
<12.5v - battery charge low
=12.5v - reasonable level of charge
>12.5v - fully charged
With a fully charged battery, headlights on for a minute or two. Voltage should drop maybe 0.2 volts and then stabilise. Should not steadily drop, certainly not below 12v otherwise battery dead.
Battery voltage - while cranking engine with a FULLY CHARGED battery:
<9v - battery knackered (or occasionally excessive current draw from a bad starter motor)
Start engine. Run at fast idle (2000 RPM). Accessories off as far as possible.
<13.8v - alternator knackered
14 - 14.5v - Charging well
>15v - alternator knackered - DANGER - regulator giving too many volts.
Continue at fast idle. Switch on some loads (e.g. Headlights, wipers, heater fan).
<13v - alternator knackered
Before condemning anything, however, check all connections are secure, especially earth connections between chassis, battery -ve and engine block, block to alternator case and the charge cable from alternator B+ terminal to battery.
Measuring voltage between the alternator b+ terminal and alternator case and comparing with battery reading can sometimes highlight bad connections (voltage drop).
These voltages are a general guide (especially the running figures under load) and some cars show more variation than others. It depends on the resistance in the wiring loom and the alternator output. It's a good idea to make a note of what's "normal" for your car while it's in good condition so you can more easily identify when a problem has appeared.
Kevin