will this mix affect the cooling cos it seemed to heat up v-quickly going over the mountain road to applecross
The maximum heath transfer efficiency of the mixed coolant is at around 2/3 Ethylene Glycol and 1/3 water. Higher EG concentration will see the heath transfer capability of the coolant going down.
This is because pure EG is thicker than water, so while it has better heat transfer properties (and higher boiling point), it will not flow as well as water and the overall effect on engine cooling will be reduced.
So 100% EG does NOT cool the engine better than mixed coolant.
Said that, for various reasons the recommended concentration is (as mentioned by others) 50%-50% which optimises various requirements such as lubrication and corrosion inhibition etc.