Hi Shell.
Can I ask before you had this problem with your car what temperature did your gauge sit at? also when say the gauge got up to 97 degrees would the fans kick in to bring down the gauge again to say 95 degrees? Just trying to see if your fans are working plus what temp your car usually runs at
When you had the water boiling where was the temparature gauge then? in the red? had the fans not kicked in?
If you are trying to clear the coolant system out there is some brilliant stuff you can buy off ebay called "Forte Coolant System Flush" it is around £10 but worth every penny. After that spend a few days dropping the clear water (dont put anti freeze in yet) then refilling so you eventually dilute the Coolant Flush out, when you are happy that the water is coming out clean drop the water again Then pour 5litres of red anti freeze in, topping up with clean water so the reservoir is at its level. Start the car leaving the reservoir cap off (with your heaters on hot) until the thermostat opens then top up with clean water. By doing this you should get the air out of the system