its climate controle, on most models, not an air con unit and a heater. Cc controles the climate in the car, if you turn part of it off, it wont work as designed, ie set it to auto select the temp you want and leave it alone within reason.
Unless its a cold morning and misted/iced up etc, then obviously use the de mist setting and the rear screen and mirror heaters.
The ac part of the system has a de humidifier built in. You may well notice the car also feels humid and uncomfortable when it mists up, and dryer and more comfortable when you turn eco off(ac unit on). Eco saves so little money/fuel it really isn't worth using, as your finding out.....
There are however some things worth checking to keep problem to a minimum, as mentioned check the car is dry inside, carpets etc esp the pass side front and rear foot wells, and that the scuttle drain, well below pollen filter hatch in scuttle pass side is clear and not holding water, and that the air vent in the boot cupboard drivers side is clear and not filled with crap.
That done, set it to auto and controle it with the temp setting, all will be well :-)