Right, the switch over to gas is based on 2 factors on the Stag ECU. Vapouriser temperature and time since start. You can also set RPM thresholds, etc. but it switches over smoothly with no tendency to stall so there's no need, IMHO.
The vapouriser temperature is close to (but lags slightly behind) coolant temperature since the vapouriser has a water jacket around it.
The vapouriser doesn't actually need to be that hot to operate. It just needs a good flow of coolant that ensures it doesn't ice up. It does take a lot of heat out of that coolant under sustained engine load (about a kilowatt during a fast motorway cruise) but rarely is that experienced on a stone cold engine, so I find 20-25 degrees C will work fine.
The engine ECU will apply enrichment after starting (even when hot) based on the assumption that it is running on petrol. These enrichments don't work for LPG (LPG doesn't condense on the walls of the inlet manifold, for example) so if you let it switch over straight after startup (whether hot or cold) it will run lumpy.
For this reason I tend to set a low switchover temperature (20-25 deg. c) but quite a long delay (15-30 seconds) to allow the startup enrichment to decay before it switches to LPG.
During the summer, it has switched to LPG before I get to the end of my road (a few hundred yards). In winter it takes perhaps 0.25-0.5 miles.
Some would argue that switching over when the vapouriser is cool will lead to more "heavy ends" being deposited in the vapouriser. That may be true, but they will surely be "boiled off" again when the engine reaches full working temperature IMHO. As long as you generally do long enough journeys that the engine gets to full working temperature I don't see a problem.
Kevin